Azoic Diazo Components Containing Phenyl Morpholine Ring.
نویسندگان
چکیده
منابع مشابه
ASYMMETRIC SYNTHESIS OF PHENYL-RING-CONTAINING ALCOHOLS USING THERMOANAEROBACTER ETHANOLICUS W110A SECONDARY ALCOHOL DEHYDROGENASE by MUSA
An enantioselective asymmetric reduction of phenyl ring-containing prochiral ketones toyield the corresponding optically active secondary alcohols was achieved with W110Asecondary alcohol dehydrogenase from Thermoanaerobacter ethanolicus (W110A TeSADH) inTris-HCl buffer using 2-propanol (30%, v/v) as cosolvent and cosubstrate. This concentration of2-propanol was crucial not only...
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In the title compound, C(11)H(14)N(2)O(3), an inter-molecular inter-action between a nitro group O atom and a neighboring benzene ring helps to stabilize the crystal structure [N⋯centroid = 3.933 (2) Å]. No classical hydrogen bonds are observed in the crystal packing.
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Aromatic π-π stacking inter-actions stabilize the crystal structure of the title compound, C(10)H(12)N(2)O(3), the perpendic-ular distance between parallel planes being 3.7721 (8) Å. The morpholine ring adopts a chair comformation.
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ژورنال
عنوان ژورنال: The Journal of the Society of Chemical Industry, Japan
سال: 1959
ISSN: 0023-2734,2185-0860
DOI: 10.1246/nikkashi1898.62.5_706